Meh, Tony Stark probably invented an anti-web solvent years ago, and no doubt keeps a vial of it tucked in a secret compartment in the suit right next to the vial of "unstable freon".
They fought some in Civil War, if i remember correctly Spidey was an employee of Stark at the time and had a Stark-tech mechanical suit that Stark had hacked to give him an advantage over spider-man
Spider-Man would definitely beat Iron Man, per the comics. Let us not forget that, while not a filthy rich industrialist, Peter Parker was, in his own right, a brilliant inventor; in spite of what the movies would lead you to believe, he created those web-shooters, not grew them.
Pfft. My baby doesn't need a stupid robot suit to beat back the machine gun wielding rabbits. I just point her butt that way and she takes care o' business.
Tony Stark invents super-strength exo-skeleton combat suit powered by ultra-miniaturized transistors and utilizing, among other advanced weapons designs, an electromagnetic field generator to focus ionized particles into a central sphere of heat and energy...
Versus:
Peter Parker, gets bitten by radioactive spider, invents glue.
The only way Spiderman could beat Iron Man mano-a-mano would be for Parker to take Stark out for a Saturday night drinking in the Bowery: Parker's metabolism would probably keep him relatively sober whilst Stark would become falling down Drunkie McDrunkerson after about six scotch rocks.
Spidey's power is embedded within his very own DNA. Iron Man can't do squat without the suit. That alone gives Spidey the upper hand.
Innate superpowers + brilliance > Money + brilliance - alcoholism
Right because the comparison:
Tony Stark invents super-strength exo-skeleton combat suit powered by ultra-miniaturized transistors and utilizing, among other advanced weapons designs, an electromagnetic field generator to focus ionized particles into a central sphere of heat and energy...
Versus:
Peter Parker, gets bitten by radioactive spider, invents glue.
The only way Spiderman could beat Iron Man mano-a-mano would be for Parker to take Stark out for a Saturday night drinking in the Bowery: Parker's metabolism would probably keep him relatively sober whilst Stark would become falling down Drunkie McDrunkerson after about six scotch rocks.
I sure would like to know.
A no-holds-barred, knock-down drag-out ends with a dead Spidey in most circumstances. Of course, said scenario never happens.