Several relatives are due to witness the execution. Among them is Marion Lewis, 57, of Mountain Home, Idaho, whose daughter Lori Lewis Rivera was shot dead by Muhammad and Malvo - who pulled the trigger is not known - at a petrol station in Kensington, Maryland.This is looking more like a reality show than a legal process.
He is being flown to Virginia by a syndicated television show and told The Washington Post he was looking forward to seeing the death penalty imposed.
"I want to see what he made me see. He forced us to look at our little girl laying in a coffin. I want to see justice done. I want to see him take a last breath...I want to be able to describe it to the rest of the family.
Muhammad will be given the chance to say some final words. Mr Lewis, who said he would have preferred a more "gruesome" execution method, wished he could say something too. "It would be short and simple: 'I'm here to see you die...son of a bitch'."